Numerical Study on Gas Transport in Shale Kerogen with Adsorption Effect Using LBM

Gas transport and storage mechanism in gas reservoirs with complex pore size distribution play a key role in gas production. In the nano-scale, during the process of density disturbance caused by depressurization development, notable output gas collides with the wall as they convey along the channel. The continuum assumption of fluid flow is therefore invalid, and taking the influence of particles to collide with solid walls into account is necessary. The effective viscosity and slip boundary conditions were introduced in the simulation. Meanwhile, because of the adsorption effect is one of the most important intrinsic properties of shale, the impact of surface adsorption on the solid wall by using Langmuir adsorption kinetics was also involved in our investigation. In this work, a unified LB model was developed for gas multiple transports and surface adsorption in nanopores. In the model, the double distribution function was employed for a coupled bulk flow and gas diffusion model. The model is valid within the range of the continuum regime to the transition regime and has been verified by the analytical solution and the results of some previously published works. The results show that (1) the driven force of the fluid, the combination coefficient of slippage and the Knudsen number of the flow have an impact on the adsorption rate, (2) adsorption effect only directly influence the local small region of the solid surface, and the induced concentration gradient makes the global concentration variation, (3) once acting the surface adsorption on the boundary, the flux falls more significant as Knudsen number increases.