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Crystal structures and magnetic properties of novel rare-earth copper sulfides, EuRCuS3 (R = Y, Gd–Lu)

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Published 16 July 2004 IOP Publishing Ltd
, , Citation Makoto Wakeshima et al 2004 J. Phys.: Condens. Matter 16 5503 DOI 10.1088/0953-8984/16/30/012

0953-8984/16/30/5503

Abstract

Novel quaternary rare-earth copper sulfides EuRCuS3 (R = Y, Gd–Lu excluding Ho, Er) have been investigated by means of x-ray diffraction, magnetic susceptibility, magnetization, and specific heat measurements. These compounds crystallize in the Eu2CuS3-type structure for R = Y, Gd–Dy and in the KZrCuS3-type structure for R = Tm–Lu. Both EuY CuS3 and EuLuCuS3 show a ferromagnetic transition and the other EuRCuS3 compounds show a ferrimagnetic transition at around 5.0 K.

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