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Vibrational State Dependence of the Photoelectron Angular Asymmetry Parameter caused by Vibronic Coupling

Published under licence by IOP Publishing Ltd
, , Citation W Domcke 1979 Phys. Scr. 19 11 DOI 10.1088/0031-8949/19/1/002

1402-4896/19/1/11

Abstract

It is shown that the dependence of the angular asymmetry parameter β on the vibrational state, which has been found in the photoelectron spectra of some polyatomic molecules, can be explained by vibronic interactions. It is proposed that measurements of β as a function of the vibrational state may be used as a tool to analyze vibronic coupling effects in photoelectron spectra.

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10.1088/0031-8949/19/1/002