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EPR of new low-symmetry sites of Ce3+ in SrF2 and BaF2

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Published under licence by IOP Publishing Ltd
, , Citation J M Baker and D M Chaplin 1979 J. Phys. C: Solid State Phys. 12 L129 DOI 10.1088/0022-3719/12/3/009

0022-3719/12/3/L129

Abstract

EPR of carefully annealed crystals of SrF2 and BaF2 containing Ce3+ revealed a large number of sites of low symmetry, which appear to arise from a small distortion of the tetragonal site Tg(Fi-). One of these sites in SrF2 has been analysed in detail; it corresponds to a rhombic site of different symmetry from that previously observed in crystals with the fluorite structure.

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10.1088/0022-3719/12/3/009