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Synthesis 1988; 1988(11): 854-858
DOI: 10.1055/s-1988-27729
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Synthesis of Side-Chain Unsaturated endo- and exo-Brevicomins. Representatives of Pheromone Analogs in the Dioxabicyclo[3.2.1]octane Series

Stefan Wershofen* , H. -D. Scharf
  • *Institut für Organische Chemie der RWTH Aachen Prof.-Pirlet-Str. 1, D-5100 Aachen, Federal Republic of Germany
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Publication Date:
20 August 2002 (online)

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The title substances endo- and exo-9 were synthesized via selective trans- and cis-opening of the epoxy tosylate 3, respectively. The tosylate 3 is easily obtainable from pentadienol 1.

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