Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1988; 1988(9): 694-697
DOI: 10.1055/s-1988-27673
DOI: 10.1055/s-1988-27673
communication
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
A Convenient Synthesis of 2-Deoxy-β-D-glucopyranosides
Further Information
Publication History
Publication Date:
18 September 2002 (online)
The O-(2-deoxy-2-phenylthio-α-D-glucopyranosyl) trichloroacetimidate α-3 was obtained from 3,4,6-tri-O-benzyl-D-glucal (1) in a two-step procedure. This compound is a powerful glucopyranosyl donor, which with typical alcohol acceptors provided mainly the corresponding 2-phenylthio-substituted 2-deoxy-β-D-glucopyranosides β-5a to β-5d. These were converted by Raney nickel treatment to the desired 2-deoxy-β-D-glucopyranosides 6 in high yields.