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Synlett 2015; 26(06): 802-806
DOI: 10.1055/s-0034-1379982
DOI: 10.1055/s-0034-1379982
letter
Lanthanide-Catalyzed Oxidative С–O Coupling of 1,3-Dicarbonyl Compounds with Diacyl Peroxides
Further Information
Publication History
Received: 21 October 2014
Accepted after revision: 17 December 2014
Publication Date:
03 February 2015 (online)
Abstract
The lanthanide-catalyzed oxidative C–O coupling of α-substituted 1,3-dicarbonyl compounds with diacyl peroxides (act both as oxidant and oxygen substituent) affords oxygen-functionalized adducts in up to 94% yield. The products of this convenient and efficient transformation serve as potentially valuable precursors for the synthesis of natural products and pharmaceuticals.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1379982.
- Supporting Information
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