Issue 12, 1995
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Calorimetric quantification of the hydrogen-bond acidity of solvents and its relationship with solvent polarity

Javier Catalán,   Javier Gómez,   José L. Saiz,   Angeles Couto,   Marisa Ferraris  and  José Laynez  

Abstract

A new solvent polarity–polarizability scale (SPP) has been used to reevaluate the hydrogen-bond acidity scale of organic solvents previously reported and has been extended to a new set of solvents. The hydrogen-bond acidity, expressed as the enthalpy term ΔacidH, has been evaluated by measuring the differences between the solvation enthalpies of N-methylimidazole and N-methylpyrrole in these solvents along with the solvent polarity–polarizability (SPP) values. The ΔacidH values for 63 solvents are reported.

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Article information

DOI
https://doi.org/10.1039/P29950002301
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1995, 2301-2305

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Calorimetric quantification of the hydrogen-bond acidity of solvents and its relationship with solvent polarity

J. Catalán, J. Gómez, J. L. Saiz, A. Couto, M. Ferraris and J. Laynez, J. Chem. Soc., Perkin Trans. 2, 1995, 2301 DOI: 10.1039/P29950002301

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