Issue 5, 1995
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Semiempirical (AM1, PM3 and SAM1) calculations of the protonation enthalpies of proton sponges related to 1,8-diaminonaphthalene. Estimation of the aqueous basicity of new designed superbases

Antonio L. Llamas-Saiz,   Concepción Foces-Foces,   Ana Martínez  and  José Elguero  

Abstract

AM1, PM3 and SAM1 calculations have been carried out on eight compounds related to 1,8-diaminonaphthalene, five known proton sponges and three new compounds (a quinolizine, an isoquinoline and a 2,7-naphthyridine). The acceptable results obtained for the correlation between pKa and protonation enthalpies for the first five compounds using either the AM1 or the SAM1 method, gives confidence to the predicted high basicity (between 19 and 22 pKa units) for the unknown compounds.

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Article information

DOI
https://doi.org/10.1039/P29950000923
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1995, 923-927

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Semiempirical (AM1, PM3 and SAM1) calculations of the protonation enthalpies of proton sponges related to 1,8-diaminonaphthalene. Estimation of the aqueous basicity of new designed superbases

A. L. Llamas-Saiz, C. Foces-Foces, A. Martínez and J. Elguero, J. Chem. Soc., Perkin Trans. 2, 1995, 923 DOI: 10.1039/P29950000923

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