Issue 5, 1987
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Identification of the pyrolysis products of some aromatic amines using microwave spectroscopy

Rinaldo Cervellati,   Giorgio Corbelli,   Alessandra Degli Esposti,   David G. Lister  and  Paolo E. Todesco  

Abstract

The pyrolysis products of some aromatic amines have been identified using microwave spectroscopy. Aniline is found to produce 1-cyanocyclopenta-1,3-diene, N-methylaniline a mixture of 1-cyanocy-clopenta-1,3-diene and benzonitrile, N,N-dimethylaniline produces benzonitrile, and N,N-dimethylpyridine-2-amine produces pyridine. In the pyrolysis of N-methylaniline the proportion of 1-cyanocyclopenta-1,3-diene to benzonitrile is estimated to be 4 : 1 from the integrated relative intensities of the low-resolution microwave band spectra of the two substances.

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Article information

DOI
https://doi.org/10.1039/P29870000585
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1987, 585-589

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Identification of the pyrolysis products of some aromatic amines using microwave spectroscopy

R. Cervellati, G. Corbelli, A. D. Esposti, D. G. Lister and P. E. Todesco, J. Chem. Soc., Perkin Trans. 2, 1987, 585 DOI: 10.1039/P29870000585

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