Issue 0, 1978
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Energy distribution and mechanism in 3-chloro-3-methyldiazirine photolysis

Juan M. Figuera,   Juan M. Pérez  and  Aurora Tobar  

Abstract

Gas-phase photolysis of pure 3-chloro-3-methyldiazirine over a wide range of pressure (133–1.015 × 105 N m–2) was performed at 334 and 313 nm. The reaction produces “hot” vinyl chloride with enough energy to subsequently decompose.

The fit of calculated (RRKM) to experimental rates for this decomposition allows determination of energy distribution functions of the vinyl chloride compatible with the data. A close examination of these functions shows that at least two pathways of vinyl chloride formation are required to explain the experimental results.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/F19787400809
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1978,74, 809-817

Permissions

Request permissions

Energy distribution and mechanism in 3-chloro-3-methyldiazirine photolysis

J. M. Figuera, J. M. Pérez and A. Tobar, J. Chem. Soc., Faraday Trans. 1, 1978, 74, 809 DOI: 10.1039/F19787400809

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements