Issue 9, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Octakis(alkylthio)-substituted phthalocyanines and their interactions with silver(I) and palladium(II) ions

AyşE Gül Gürek  and  Özer Bekaroǧlu  

Abstract

Metal-free phthalocyanines and metal phthalocyaninates (M = Ni, Cu, Co or Zn) carrying eight alkylthio-groups on peripheral positions have been synthesised from 4,5-bis(alkylthio)phthalonitrile and 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu) or the corresponding anhydrous metal salt [NiCl2, CuCl, CoCl2 or Zn(O2CMe)2]. The resulting compounds reacted with silver(I) or palladium(II) salts to form complexes with a phthalocyanine:metal ratio of 1 : 4. Spectrophotochemical investigation of these reactions revealed that complexation with AgI results in aggregation, while the addition of PdII destroys the aggregation and yields a new Q band at 720 nm.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9940001419
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1419-1423

Permissions

Request permissions

Octakis(alkylthio)-substituted phthalocyanines and their interactions with silver(I) and palladium(II) ions

A. G. Gürek and Ö. Bekaroǧlu, J. Chem. Soc., Dalton Trans., 1994, 1419 DOI: 10.1039/DT9940001419

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements