Issue 11, 1978
From the journal:

Journal of the Chemical Society, Dalton Transactions

Complexes of osmium(VI) with catechol and substituted catechols

Alastair J. Nielson  and  William P. Griffith  

Abstract

Osmium tetraoxide reacts with catechols, R(OH)2-o, to give the tris(catecholato)-species [Os(O2R)3] and the polymers [{OsO(O2R)2}n], while in the presence of pyridine or substituted pyridines (L)trans-[OsO2(O2R)L2] complexes are formed. Reaction of cis-[OsO4(OH)2]2– or trans-[OsO2(OH)4]2– with catechols yields salts of trans-[OsO2(O2R)2]2–. The Raman, i.r., 1H and 13C n.m.r., and mass spectra of the products are reported and the structures deduced. The relevance of some of these complexes to the reaction of OsO4 with phenolic material in plant tissue is briefly discussed.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9780001501
Article type
Paper

J. Chem. Soc., Dalton Trans., 1978, 1501-1506

Permissions

Request permissions

Complexes of osmium(VI) with catechol and substituted catechols

A. J. Nielson and W. P. Griffith, J. Chem. Soc., Dalton Trans., 1978, 1501 DOI: 10.1039/DT9780001501

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements