SCHEDULED MAINTENANCE
The effect of surface hydrophobicity and hydrophilicity on ion–ion interactions at water–solid interfaces†
bc
Ying
Jiang
*acd
Abstract
Condensation and arrangement of ions at water–solid interfaces are of great importance in the formation of electrical double layers (EDL) and the transport of ions under a confined geometry. So far, the microscopic understanding of interfacial ion configurations is still far from complete, especially when the local ion concentration is high and ion–ion interactions become prominent. In this study, we directly visualized alkali metal cations within the hydrogen-bonding network of water on graphite and Cu(111)-supported graphene surfaces, using qPlus-based noncontact atomic force microscopy (NC-AFM). We found that the codeposition of the alkali cations and water molecules on the hydrophobic graphite surface leads to the formation of an ion-doped bilayer hexagonal ice (BHI) structure, where the ions are repelled from each other and scattered in a disordered distribution. In contrast, the hydrated alkali cations aggregate in one dimension on the more hydrophilic graphene/Cu(111) surface, forming a nematic state with a long-range order. Such a nematic state arises from the delicate interplay between water–ion and water–water interactions under surface confinement. These results reveal the high sensitivity of ion–ion interactions and ionic ordering to the surface hydrophobicity and hydrophilicity.
- This article is part of the themed collection: Water at interfaces
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