Issue 46, 2023
From the journal:

Chemical Communications

Photoinduced C(sp3)–H borylation of alkanes mediated by copper(ii) chloride†

Wen Fang,‡a   Huai-Qin Wang,‡a   Wei Zhou,a   Zhi-Wen Luoa  and  Jian-Jun Dai ORCID logo *a  

* Corresponding authors

a School of Food and Biological Engineering, Hefei University of Technology, Hefei 230009, China
E-mail: daijj@hfut.edu.cn

Abstract

Alkyl boronic acid and its derivatives are important motifs in organic synthesis and pharmaceuticals. Herein, we report a photoinduced, CuCl2 mediated C(sp3)–H borylation of unactivated alkanes. This protocol features mild reaction conditions, readily available reagents, and gram-scalability.

Graphical abstract: Photoinduced C(sp3)–H borylation of alkanes mediated by copper(ii) chloride

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Article information

DOI
https://doi.org/10.1039/D3CC01767B
Article type
Communication
Submitted
11 Apr 2023
Accepted
16 May 2023
First published
16 May 2023

Chem. Commun., 2023,59, 7108-7111

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Photoinduced C(sp3)–H borylation of alkanes mediated by copper(II) chloride

W. Fang, H. Wang, W. Zhou, Z. Luo and J. Dai, Chem. Commun., 2023, 59, 7108 DOI: 10.1039/D3CC01767B

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