Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Kira M. Fahy; Mohammad Rasel Mian; Megan C. Wasson; Florencia A. Son; Timur Islamoglu; Omar K. Farha

doi:10.1039/D2CC00925K

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Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework†

Kira M. Fahy,

^a Mohammad Rasel Mian,^a Megan C. Wasson,

^a Florencia A. Son,

^a Timur Islamoglu

*^a and Omar K. Farha

*^ab

Author affiliations

* Corresponding authors

^a International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail: timur.islamoglu@northwestern.edu, o-farha@northwestern.edu

^b Department of Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA

Abstract

Metal–organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo.

This article is part of the themed collection: Emerging Trends in MOFs

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DOI: https://doi.org/10.1039/D2CC00925K
Article type: Communication
Submitted: 15 Feb 2022
Accepted: 25 Feb 2022
First published: 07 Mar 2022

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Chem. Commun., 2022,58, 4028-4031

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Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

K. M. Fahy, M. R. Mian, M. C. Wasson, F. A. Son, T. Islamoglu and O. K. Farha, Chem. Commun., 2022, 58, 4028 DOI: 10.1039/D2CC00925K

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Chemical Communications

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework†

Abstract

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Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

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