Issue 42, 2021
From the journal:

Dalton Transactions

Ensembles from silver clusters and cucurbit[6]uril-containing linkers†

Na-Na Li,ab   Ming Yang,b   Xiao-Jie Xu,c   Xi-Yan Dong, ORCID logo *ab   Si Li*b  and  Shuang-Quan Zang ORCID logo ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Henan Polytechnic University Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo 454000, China

b Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

c School of Physics and Electronic Information Engineering, Henan Polytechnic University, Jiaozuo 454000, China

Abstract

In this work, organic supramolecular linkers involving cucubit[6]urils CB[6] and N,N′-hexamethylene-bis(pyrazinyl hexafluorophosphate) (BPHF@CB[6]) were utilized to assemble dodenuclear silver chalcogenolate clusters into three one-dimensional (1D) materials under different synthesis conditions. These three crystal structures of CB[6]-based sliver cluster-organic rotaxane frameworks were well resolved, and their emission properties were investigated systematically. This construction strategy involving organic supramolecular linkers gives a new methodology for cluster-assembled materials with intriguing structural and functional properties.

Graphical abstract: Ensembles from silver clusters and cucurbit[6]uril-containing linkers

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Article information

DOI
https://doi.org/10.1039/D1DT02505H
Article type
Paper
Submitted
29 Jul 2021
Accepted
29 Sep 2021
First published
29 Sep 2021

Dalton Trans., 2021,50, 15267-15273

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Ensembles from silver clusters and cucurbit[6]uril-containing linkers

N. Li, M. Yang, X. Xu, X. Dong, S. Li and S. Zang, Dalton Trans., 2021, 50, 15267 DOI: 10.1039/D1DT02505H

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