Issue 19, 2021

Organophosphorus decorated lithium borate and phosphate salts with extended π-conjugated backbone

Abstract

Several new bifunctional salts, Li[B(DPN)2], Li[B(DPN)(ox)] and Li[P(DPN)3], have been prepared from the phosphorus(V)-containing chelating ligand 2,3-dihydroxynaphthalene-1,4-(tetraethyl)bis(phosphonate) (H2-DPN). The new lithium salts were characterized by a variety of spectroscopic techniques. Both H2-DPN and Li[B(DPN)2] have been structurally characterized by X-ray crystallographic methods. These salts are related to materials being examined for use in electrolyte solutions for lithium-ion battery (LIB) applications.

Graphical abstract: Organophosphorus decorated lithium borate and phosphate salts with extended π-conjugated backbone

Supplementary files

Article information

Article type
Paper
Submitted
22 Feb 2021
Accepted
19 Apr 2021
First published
28 Apr 2021

Dalton Trans., 2021,50, 6667-6672

Author version available

Organophosphorus decorated lithium borate and phosphate salts with extended π-conjugated backbone

E. Delgado Rosario, M. F. Rectenwald, J. R. Gaffen, A. L. Rheingold and J. D. Protasiewicz, Dalton Trans., 2021, 50, 6667 DOI: 10.1039/D1DT00601K

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