Issue 79, 2021
From the journal:

Chemical Communications

Carbonylative coupling of simple alkanes and alkenes enabled by organic photoredox catalysis†

Ling Chen,a   Jing Hou, ORCID logo *a   Ming Zheng,a   Le-Wu Zhan,a   Wan-Ying Tang*a  and  Bin-Dong Li*a  

* Corresponding authors

a College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
E-mail: libindong@njust.edu.cn, chmhouj@njust.edu.cn, zhanlewu@njust.edu.cn

Abstract

A visible-light-driven direct carbonylative coupling of simple alkanes and alkenes via the combination of a hydrogen atom transfer process and photoredox catalysis has been demonstrated. Employing the N-alkoxyazinium salt as the oxidant and the precursor of an oxygen radical, a variety of α,β-unsaturated ketones could be obtained in a metal-free fashion.

Graphical abstract: Carbonylative coupling of simple alkanes and alkenes enabled by organic photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/D1CC04138J
Article type
Communication
Submitted
30 Jul 2021
Accepted
06 Sep 2021
First published
07 Sep 2021

Chem. Commun., 2021,57, 10210-10213

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Carbonylative coupling of simple alkanes and alkenes enabled by organic photoredox catalysis

L. Chen, J. Hou, M. Zheng, L. Zhan, W. Tang and B. Li, Chem. Commun., 2021, 57, 10210 DOI: 10.1039/D1CC04138J

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