Retracted Article: Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(I) and silver(I) complexes

Jas S. Ward; Antonio Frontera; Kari Rissanen

doi:10.1039/D1CC01505B

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Retracted Article: Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(i) and silver(i) complexes†

Jas S. Ward,

*^a Antonio Frontera

^b and Kari Rissanen

*^a

Author affiliations

* Corresponding authors

^a University of Jyvaskyla, Department of Chemistry, Jyväskylä 40014, Finland
E-mail: james.s.ward@jyu.fi, kari.t.rissanen@jyu.fi

^b Department of Chemistry, Universitat de les Illes Balears, Crts de Valldemossa km 7.6, Palma de Mallorca Baleares 07122, Spain

Abstract

The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I⁺) complexes and studying their ¹⁵N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.