Issue 100, 2020

Photoredox radical borylation of electron-deficient alkenes with NHC-boranes

Abstract

An efficient photoredox radical borylation of electron-deficient Morita–Baylis–Hillman type alkenes is achieved to afford multi-functionalized allylic boranes. The reaction demonstrates a wide substrate scope and showcases excellent functional group tolerance. It has advantages over the traditional ionic hydroboration methods in the construction of allylic boranes in terms of simple operation, mild conditions, and step-economy.

Graphical abstract: Photoredox radical borylation of electron-deficient alkenes with NHC-boranes

Supplementary files

Article information

Article type
Communication
Submitted
20 Oct 2020
Accepted
20 Nov 2020
First published
20 Nov 2020

Chem. Commun., 2020,56, 15647-15650

Photoredox radical borylation of electron-deficient alkenes with NHC-boranes

C. Zhu, S. Gao, W. Li and C. Zhu, Chem. Commun., 2020, 56, 15647 DOI: 10.1039/D0CC06966C

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