A conceptually novel intramolecular allylic alkylation strategy is developed for the synthesis of carbazoles and dibenzothiophenes. In an unusual event, palladium catalyses the formation of π-allylpalladium complexes of the respective (2-methylindol-3-yl)allyl acetates and subsequently facilitates the benzannulation process.
S. Yadav and S. S. V. Ramasastry, Chem. Commun., 2021, 57, 77 DOI: 10.1039/D0CC06695H
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