Issue 85, 2020
From the journal:

Chemical Communications

A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages†

Matthew L. Schneider, ORCID logo a   Oliver M. Linder-Patton ORCID logo a  and  Witold M. Bloch ORCID logo *a  

* Corresponding authors

a Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia
E-mail: witold.bloch@adelaide.edu.au

Abstract

A Cu4L4 metal–organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline–copper coordination and possess a tunable porosity based on the rate of deprotection.

Graphical abstract: A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages

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Article information

DOI
https://doi.org/10.1039/D0CC05349J
Article type
Communication
Submitted
06 Aug 2020
Accepted
20 Sep 2020
First published
21 Sep 2020

Chem. Commun., 2020,56, 12969-12972

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A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages

M. L. Schneider, O. M. Linder-Patton and W. M. Bloch, Chem. Commun., 2020, 56, 12969 DOI: 10.1039/D0CC05349J

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