Issue 70, 2020
From the journal:

Chemical Communications

A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization†

Ravi Yadav, ORCID logo a   Bhupendra Goswami,a   Thomas Simler, ORCID logo a   Christoph Schoo, ORCID logo a   Stephan Reichl,b   Manfred Scheer ORCID logo b  and  Peter W. Roesky ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu

b Institute of Inorganic Chemistry, University of Regensburg, Universitätsstraße 31, 93040 Regensburg, Germany

Abstract

Pentaphosphaferrocene, [Cp*Fe(η5-P5)] (Cp* = η5-C5Me5), was used as a polyphosphorus source to obtain germylene–polyphosphide complexes. A stepwise reactivity was observed between the di-germylene, [LGe–GeL] (L = {PhC(NtBu)2}), and [Cp*Fe(η5-P5)]. Firstly, reductive homolytic cleavage of the Ge–Ge single bond in [LGe–GeL] led to [(LGe)2{(μ,η4-P5)FeCp*}]. This complex showed an unprecedented isomerization.

Graphical abstract: A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization

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Article information

DOI
https://doi.org/10.1039/D0CC03920A
Article type
Communication
Submitted
04 Jun 2020
Accepted
13 Jul 2020
First published
04 Aug 2020
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2020,56, 10207-10210

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A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization

R. Yadav, B. Goswami, T. Simler, C. Schoo, S. Reichl, M. Scheer and P. W. Roesky, Chem. Commun., 2020, 56, 10207 DOI: 10.1039/D0CC03920A

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