Issue 65, 2020

Ligand-enabled gold-catalyzed 1,2-heteroarylation of alkenes

Abstract

By adopting the interplay between ligand-enabled Au(I)/Au(III) catalysis and the unique π-activation mode of gold complexes, a highly coveted 1,2-heteroarylation of alkenes has been accomplished. The present ligand-enabled approach not only circumvents the requirement for strong sacrificial oxidants or photocatalysts but also operates under mild reaction conditions by utilizing simple and non-prefunctionalized aryl coupling partners.

Graphical abstract: Ligand-enabled gold-catalyzed 1,2-heteroarylation of alkenes

Supplementary files

Article information

Article type
Communication
Submitted
26 May 2020
Accepted
07 Jul 2020
First published
07 Jul 2020

Chem. Commun., 2020,56, 9304-9307

Ligand-enabled gold-catalyzed 1,2-heteroarylation of alkenes

A. G. Tathe, C. C. Chintawar, V. W. Bhoyare and N. T. Patil, Chem. Commun., 2020, 56, 9304 DOI: 10.1039/D0CC03707A

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