[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Ai-Min Li; Yi Wang; Peter Y. Zavalij; Fu Chen; Alvaro Muñoz-Castro; Bryan W. Eichhorn

doi:10.1039/D0CC03656K

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[CpRuPb₁₁]³⁻ and [Cu@CpRuPb₁₁]²⁻: centered and non-centered transition-metal substituted zintl icosahedra†

Ai-Min Li,

^a Yi Wang,

^a Peter Y. Zavalij,

^a Fu Chen,^a Alvaro Muñoz-Castro

^b and Bryan W. Eichhorn

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
E-mail: eichhorn@umd.edu

^b Laboratorio de Química Inorgánica y Materiales Moleculares, Facultad de Ingeniería, Universidad Autonoma de Chile, Llano Subercaseaux 2801, San Miguel, Santiago, Chile

Abstract

Cluster anions [Cp*RuPb₁₁]³⁻ (1) and [Cu@Cp*RuPb₁₁]²⁻ (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C_5v point symmetry and are static on the ²⁰⁷Pb NMR time scale in solution.

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Article information

DOI: https://doi.org/10.1039/D0CC03656K
Article type: Communication
Submitted: 24 Jun 2020
Accepted: 06 Aug 2020
First published: 06 Aug 2020

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Chem. Commun., 2020,56, 10859-10862

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[CpRuPb₁₁]³⁻ and [Cu@CpRuPb₁₁]²⁻: centered and non-centered transition-metal substituted zintl icosahedra

A. Li, Y. Wang, P. Y. Zavalij, F. Chen, A. Muñoz-Castro and B. W. Eichhorn, Chem. Commun., 2020, 56, 10859 DOI: 10.1039/D0CC03656K

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