Issue 56, 2020
From the journal:

Chemical Communications

Rhodium(iii)-catalyzed diamidation of olefins via amidorhodation and further amidation†

Jinlei Wang,a   Guangfan Zhenga  and  Xingwei Li*a  

* Corresponding authors

a Key Laboratory of Applied Surface and Colloid Chemistry of MOE, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China
E-mail: lixw@snnu.edu.cn

Abstract

Rh(III)-catalyzed synthesis of vicinal diamides has been realized via elaboration of an authenticated Rh–C(sp3) species generated via initial intramolecular amidorhodation of olefins. The second amidation was achieved using both electrophilic and nucleophilic amidating reagents. The reactions proceeded under mild conditions with good yield, broad substrate scope, and excellent functional-group tolerance.

Graphical abstract: Rhodium(iii)-catalyzed diamidation of olefins via amidorhodation and further amidation

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Article information

DOI
https://doi.org/10.1039/D0CC00952K
Article type
Communication
Submitted
06 Feb 2020
Accepted
25 Jun 2020
First published
26 Jun 2020

Chem. Commun., 2020,56, 7809-7812

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Rhodium(III)-catalyzed diamidation of olefins via amidorhodation and further amidation

J. Wang, G. Zheng and X. Li, Chem. Commun., 2020, 56, 7809 DOI: 10.1039/D0CC00952K

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