Issue 19, 2019

Synthesis of cyclic gem-dinitro compounds via radical nitration of 1,6-diynes with Fe(NO3)3·9H2O

Abstract

Cyclic gem-dinitro compounds were obtained via nitration of 1,6-diynes using Fe(NO3)3·9H2O as the nitrating agent. The reaction proceeds at room temperature using a cheap nitrating agent. A number of gem-dinitro cyclic compounds were obtained in moderate to good yields. The reaction offers an easy and convenient protocol to prepare gem-dinitro compounds, which are not easily obtained via the known procedures.

Graphical abstract: Synthesis of cyclic gem-dinitro compounds via radical nitration of 1,6-diynes with Fe(NO3)3·9H2O

Supplementary files

Article information

Article type
Communication
Submitted
21 Feb 2019
Accepted
23 Apr 2019
First published
23 Apr 2019

Org. Biomol. Chem., 2019,17, 4725-4728

Synthesis of cyclic gem-dinitro compounds via radical nitration of 1,6-diynes with Fe(NO3)3·9H2O

X. Yi, K. Chen, W. Chen, W. Chen, M. Liu and H. Wu, Org. Biomol. Chem., 2019, 17, 4725 DOI: 10.1039/C9OB00431A

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