Issue 19, 2019
From the journal:

CrystEngComm

Coordination polymers based on pyrazole-4-carboxaldehyde-containing Cu3N6 metallacycles as building units†

David I. Kreiger, ORCID logo a   Logesh Mathivathanan ORCID logo a  and  Raphael G. Raptis ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th St, Miami, FL, USA
E-mail: Raphael.raptis@fiu.edu

Abstract

Five crystal structures containing trinuclear Cu(II)-4-formyl pyrazolato units are reported: a 0-D Cu3 complex ((Ph4P)2[1]) was prepared in the presence of terminal chloride ligands, a 3D polymer with dia topology and 3-fold interpenetrated structure ([2](CF3SO3)2) involved 1,2-bipyridylethylene (bpe) linkers, while a second 1-D polymer ([3](CF3SO3)2) formed by linking SBUs via formyl group coordination. Two 3D polymers ([4](CF3SO3)2 and [5](ClO4)2) with novel topologies consist of 14-nodal 38,42,54-c and 3-nodal 3,3,4-c nets, respectively.

Graphical abstract: Coordination polymers based on pyrazole-4-carboxaldehyde-containing Cu3N6 metallacycles as building units

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CE00421A
Article type
Paper
Submitted
21 Mar 2019
Accepted
12 Apr 2019
First published
12 Apr 2019

CrystEngComm, 2019,21, 3047-3055

Author version available


Download author version (PDF)

Permissions

Request permissions

Coordination polymers based on pyrazole-4-carboxaldehyde-containing Cu3N6 metallacycles as building units

D. I. Kreiger, L. Mathivathanan and R. G. Raptis, CrystEngComm, 2019, 21, 3047 DOI: 10.1039/C9CE00421A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements