Issue 93, 2019
From the journal:

Chemical Communications

Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction†

Shuai Wang,a   Cheng Yang,a   Shuo Suna  and  Jianbo Wang ORCID logo *ab  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: wangjb@pku.edu.cn

b The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A catalyst-free electrochemical cross-coupling reaction of aryl halides with trialkyl phosphite has been developed. This reaction proceeds in an undivided cell with a low-cost Ni anode and a graphite cathode under mild and neutral conditions. A wide range of functional groups are well-tolerated and the phosphorylated product can be obtained on the gram scale, showing that this transformation has the potential to be a valuable method for the construction of aromatic carbon–phosphorus bonds.

Graphical abstract: Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC07069A
Article type
Communication
Submitted
10 Sep 2019
Accepted
28 Oct 2019
First published
29 Oct 2019

Chem. Commun., 2019,55, 14035-14038

Permissions

Request permissions

Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction

S. Wang, C. Yang, S. Sun and J. Wang, Chem. Commun., 2019, 55, 14035 DOI: 10.1039/C9CC07069A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements