Issue 76, 2019
From the journal:

Chemical Communications

Water-mediated C–H activation of arenes with secure carbene precursors: the reaction and its application†

Ruifang Nie,‡a   Ruizhi Lai,‡a   Songyang Lv,a   Yingying Xu,a   Li Guo,a   Qiantao Wang*a  and  Yong Wu ORCID logo *a  

* Corresponding authors

a Sichuan Engineering Laboratory for Plant-Sourced Drug and Research Center for Drug Industrial Technology, Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu, China
E-mail: qwang@scu.edu.cn, wyong@scu.edu.cn

Abstract

A water-mediated C–H activation using sulfoxonium ylides is reported, providing a general, green and step-economic approach to construct a C–C bond and varieties of useful N-heterocycle scaffolds. Notably, the “water-mediated” activation, in contrast to that in organic solvents, shows great potential in pharmaceutical, biochemistry and chemical industries.

Graphical abstract: Water-mediated C–H activation of arenes with secure carbene precursors: the reaction and its application

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Article information

DOI
https://doi.org/10.1039/C9CC05804D
Article type
Communication
Submitted
26 Jul 2019
Accepted
27 Aug 2019
First published
27 Aug 2019

Chem. Commun., 2019,55, 11418-11421

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Water-mediated C–H activation of arenes with secure carbene precursors: the reaction and its application

R. Nie, R. Lai, S. Lv, Y. Xu, L. Guo, Q. Wang and Y. Wu, Chem. Commun., 2019, 55, 11418 DOI: 10.1039/C9CC05804D

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