Issue 66, 2019

Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules

Abstract

Single-tailed and gemini-type supra-gelators were facilely fabricated via the conjugation of the D- or L-enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C12BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achieved via the spontaneous assembly of the formed supra-gelators into supramolecular chiral hydrogels.

Graphical abstract: Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2019
Accepted
24 Jul 2019
First published
24 Jul 2019

Chem. Commun., 2019,55, 9861-9864

Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules

P. Sun, S. Ren, A. Wu, N. Sun, L. Shi and L. Zheng, Chem. Commun., 2019, 55, 9861 DOI: 10.1039/C9CC05598C

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