Issue 65, 2019
From the journal:

Chemical Communications

Synthesis and reactivity of asymmetric Cr(i) dinitrogen complexes supported by cyclopentadienyl–phosphine ligands†

Jiapeng Li, ORCID logo ‡a   Jianhao Yin, ORCID logo ‡a   Gao-Xiang Wang, ORCID logo ‡a   Zhu-Bao Yin, ORCID logo a   Wen-Xiong Zhang ORCID logo *a  and  Zhenfeng Xi ORCID logo *a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: wx_zhang@pku.edu.cn, zfxi@pku.edu.cn

Abstract

Asymmetric trinuclear and dinuclear Cr(I) dinitrogen complexes bearing cyclopentadienyl–phosphine ligands were synthesized via reduction of their corresponding Cr(II) chloride complexes in the presence of N2. Oxidative addition reactions of single, double and triple bonds are found to take place on the low-valent Cr(I) centre.

Graphical abstract: Synthesis and reactivity of asymmetric Cr(i) dinitrogen complexes supported by cyclopentadienyl–phosphine ligands

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Article information

DOI
https://doi.org/10.1039/C9CC02960E
Article type
Communication
Submitted
16 Apr 2019
Accepted
16 Jul 2019
First published
17 Jul 2019

Chem. Commun., 2019,55, 9641-9644

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Synthesis and reactivity of asymmetric Cr(I) dinitrogen complexes supported by cyclopentadienyl–phosphine ligands

J. Li, J. Yin, G. Wang, Z. Yin, W. Zhang and Z. Xi, Chem. Commun., 2019, 55, 9641 DOI: 10.1039/C9CC02960E

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