A dual-responsive luminescent metal–organic framework as a recyclable luminescent probe for the highly effective detection of pyrophosphate and nitrofurantoin

Hui Li; Jie Ren; Xiufang Xu; Liangmin Ning; Ruoyan Tong; Yao Song; Shengyun Liao; Wen Gu; Xin Liu

doi:10.1039/C9AN00718K

A dual-responsive luminescent metal–organic framework as a recyclable luminescent probe for the highly effective detection of pyrophosphate and nitrofurantoin†‡

Hui Li,^a Jie Ren,^a Xiufang Xu,

^a Liangmin Ning,^a Ruoyan Tong,^a Yao Song,^a Shengyun Liao,*^b Wen Gu*^a and Xin Liu

*^a

Author affiliations

* Corresponding authors

^a Collaborative Innovation Center of Chemical Science and Engineering, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China
E-mail: liuxin64@nankai.edu.cn, guwen68@nankai.edu.cn

^b Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, School of Chemistry and Chemical Engineering, Tianjin University of Technology, No. 391 Binshuixi Road, Tianjin 300384, China
E-mail: 18202587221@163.com

Abstract

Pyrophosphate (PPi) is a significant biological anion, and its abnormal level in the human body is regarded as a signal of some diseases. Herein, we developed a method for the detection of PPi using a luminescent ZTMOF-1 via the luminescence turn-on effect. PPi formed hydrogen bonds with the phenyl and pyridine rings in the framework, and ZTMOF-1 could discriminately detect PPi among other phosphorus oxides in both an aqueous solution and a physiological environment. In addition, to the best of our knowledge, this is the first report on the use of a regenerable MOF-based luminescent sensor for the detection of PPi. Moreover, ZTMOF-1 showed an excellent luminescence quenching response to nitrofurantoin (NFT) over other drugs with the detection limit of 0.175 μM. This study presents a dual-responsive regenerable luminescent probe for the detection of PPi and NFT.

This article is part of the themed collection: Analyst Recent HOT articles

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9AN00718K
Article type: Paper
Submitted: 20 Apr 2019
Accepted: 09 Jun 2019
First published: 12 Jun 2019

Download Citation

Analyst, 2019,144, 4513-4519

Permissions

Request permissions

A dual-responsive luminescent metal–organic framework as a recyclable luminescent probe for the highly effective detection of pyrophosphate and nitrofurantoin

H. Li, J. Ren, X. Xu, L. Ning, R. Tong, Y. Song, S. Liao, W. Gu and X. Liu, Analyst, 2019, 144, 4513 DOI: 10.1039/C9AN00718K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Analyst

A dual-responsive luminescent metal–organic framework as a recyclable luminescent probe for the highly effective detection of pyrophosphate and nitrofurantoin†‡

Abstract

Supplementary files

Article information

Download Citation

Permissions

A dual-responsive luminescent metal–organic framework as a recyclable luminescent probe for the highly effective detection of pyrophosphate and nitrofurantoin

Social activity

Search articles by author

Spotlight

Advertisements