Issue 24, 2018

Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

Abstract

Multifunctional vinyl sulfonates and vinyl sulfonamides were conveniently synthesized and assessed in thiol-Michael crosslinking polymerizations. The monomer reactivities, mechanical behavior and hydrolytic properties were analyzed and compared with those of analogous thiol–acrylate polymerizations. Materials with a broad range of mechanical properties and diverse hydrolytic stabilities were obtained.

Graphical abstract: Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2018
Accepted
28 Feb 2018
First published
07 Mar 2018

Chem. Commun., 2018,54, 3034-3037

Multifunctional monomers based on vinyl sulfonates and vinyl sulfonamides for crosslinking thiol-Michael polymerizations: monomer reactivity and mechanical behavior

J. Sinha, M. Podgórski, S. Huang and C. N. Bowman, Chem. Commun., 2018, 54, 3034 DOI: 10.1039/C8CC00782A

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