Abstract
A pyrene-based probe bearing benzothiazole ionophore (Py-BTZ) was synthesised as a “turn-on” fluorescent chemosensor for the detection of Fe3+ and Fe2+ ions in CH3CN: H2O (1: 1, v/v) solvent mixes. The chemosensor showed optical as well as colorimetric changes towards Fe3+ and Fe2+ ions along with a remarkable enhancement in fluorescence emission. The detection limit of Py-BTZ towards Fe3+ and Fe2+ ions was found to be 2.61 μM and 2.06 μM, respectively. The binding of Py-BTZ with Fe3+ and Fe2+ was determined by using FT-IR experiments. Interestingly, Py-BTZ shows aggregation induced emission enhancement (AIEE) properties in polar solvent mixes such as CH3CN: H2O (1: 1, v/v).
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Acknowledgments
R. S. B acknowledges financial support from CSIR, New Delhi under the SRA scheme [13(8772)-A/2015-Pool]. S. V. B. (RMIT) acknowledges financial support from the Australian Research Council under a Future Fellowship Scheme (FT110100152). S. V. B. (IICT) is grateful for financial support from the SERB (Project Code: SB/S1/IC-009/2014), New Delhi, India. A. L. P. procured Gaussian 09 under the DST-FIST Scheme (Sanction No. FS/FST/PSI-018/2009).
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Padghan, S.D., Puyad, A.L., Bhosale, R.S. et al. A pyrene based fluorescent turn-on chemosensor: aggregation-induced emission enhancement and application towards Fe3+ and Fe2+ recognition. Photochem Photobiol Sci 16, 1591–1595 (2017). https://doi.org/10.1039/c7pp00329c
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DOI: https://doi.org/10.1039/c7pp00329c