Issue 18, 2017
From the journal:

Dalton Transactions

Self-assembly and anion sensing of metal–organic [M6L2] cages from fluorescent triphenylamine tri-pyrazoles with dipalladium(ii,ii) corners†

Yu Cui,a   Zi-Man Chen,a   Xuan-Feng Jiang,a   Jin Tong*a  and  Shu-Yan Yu ORCID logo *a  

* Corresponding authors

a Beijing Key Laboratory for Green Catalysis and Separation, Laboratory for Self-Assembly Chemistry, Department of Chemistry and Chemical Industry, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
E-mail: selfassembly@bjut.edu.cn

Abstract

Three hexametal-organic cages [(N^N)6Pd6L2]6+ with syn, syn, syn conformation were synthesized via the coordination of tris(4-(1H-pyrazol-3-yl)phenyl)amine ligands and [(N^N)2Pd2(NO3)2](NO3)2 dimetallic corners (N^N = 2,2′-bipyridine for 1; 4,4′-dimethylbipyridine for 2; 1,10-phenanthroline for 3). These hexametal-organic cages exhibit anion sensing toward HSO3− in aqueous solution via fluorescent titration and NMR spectroscopy studies.

Graphical abstract: Self-assembly and anion sensing of metal–organic [M6L2] cages from fluorescent triphenylamine tri-pyrazoles with dipalladium(ii,ii) corners

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Article information

DOI
https://doi.org/10.1039/C7DT00179G
Article type
Communication
Submitted
16 Jan 2017
Accepted
03 Apr 2017
First published
04 Apr 2017

Dalton Trans., 2017,46, 5801-5805

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Self-assembly and anion sensing of metal–organic [M6L2] cages from fluorescent triphenylamine tri-pyrazoles with dipalladium(II,II) corners

Y. Cui, Z. Chen, X. Jiang, J. Tong and S. Yu, Dalton Trans., 2017, 46, 5801 DOI: 10.1039/C7DT00179G

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