Issue 13, 2016

Surface-initiated SET-LRP mediated by mussel-inspired polydopamine chemistry for controlled building of novel core–shell magnetic nanoparticles for highly-efficient uranium enrichment

Abstract

This study presents an effective and facile strategy by integrating surface-initiated single electron transfer living radical polymerization (SET-LRP) with mussel-inspired polydopamine (PDA) chemistry for controlled building of a novel class of core–shell magnetic nanoparticles (MNPs) for highly-efficient uranium enrichment. The strategy initially involves the deposition of a PDA encapsulation layer by spontaneous self-polymerization on the Fe3O4 core, which serves as a safety shell and provides an enabling platform for anchoring of 2-bromoisobutyryl bromide (BiBB) to form macro-initiators. Dense polyacrylonitrile (PAN) brushes are grown from the BiBB-attached PDA shell via SET-LRP using Cu(0)/Me6TREN as a catalytic/ligand system, followed by conversion to amidoxime (AO) functionalized polymer brushes. The core–shell Fe3O4@PDA@PAO MNPs exhibit favorable superparamagnetic characteristics and a fast response within 6 s under an applied magnetic field. Due to the strong binding ability of AO ligands, Fe3O4@PDA@PAO shows a remarkable adsorption capacity (qe = 162.5 mg g−1) toward uranyl ions under optimal pH conditions. A study on the adsorption kinetics suggests that the adsorption process might conform to the pseudo-second-order model. We conclude that the Fe3O4@PDA@PAO MNPs have the potential for effective enrichment and magnetic separation of uranium, and the integrative synthetic strategy combining the SET-LRP technique and PDA chemistry would bring extensive opportunities for versatile surface modification of nanomaterials for more demanding applications.

Graphical abstract: Surface-initiated SET-LRP mediated by mussel-inspired polydopamine chemistry for controlled building of novel core–shell magnetic nanoparticles for highly-efficient uranium enrichment

Supplementary files

Article information

Article type
Paper
Submitted
20 Jan 2016
Accepted
05 Mar 2016
First published
07 Mar 2016

Polym. Chem., 2016,7, 2427-2435

Surface-initiated SET-LRP mediated by mussel-inspired polydopamine chemistry for controlled building of novel core–shell magnetic nanoparticles for highly-efficient uranium enrichment

Y. Yang, J. Wang, F. Wu, G. Ye, R. Yi, Y. Lu and J. Chen, Polym. Chem., 2016, 7, 2427 DOI: 10.1039/C6PY00109B

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