Issue 35, 2016

Synthesis of esters via sp3 C–H functionalisation

Abstract

Oxidative C–O bond formation via sp3 C–H functionalisation represents an attractive approach for the synthesis of esters. This review focuses on the recent advances of sp3 C–H bond functionalisation strategies for ester synthesis from unconventional precursors using transition metal/metal free catalysts in combination with various oxidants. Various classes of esters and the mechanisms of their formation are discussed with numerous examples.

Graphical abstract: Synthesis of esters via sp3 C–H functionalisation

Article information

Article type
Review Article
Submitted
09 Jun 2016
Accepted
18 Jul 2016
First published
19 Jul 2016

Org. Biomol. Chem., 2016,14, 8178-8211

Synthesis of esters via sp3 C–H functionalisation

G. Majji, S. K. Rout, S. Rajamanickam, S. Guin and B. K. Patel, Org. Biomol. Chem., 2016, 14, 8178 DOI: 10.1039/C6OB01250G

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