Issue 8, 2017

Type-inversion as a working mechanism of high voltage MAPbBr3(Cl)-based halide perovskite solar cells

Abstract

Using several metals with different work functions as solar cell back contact we identify majority carrier type inversion in methylammonium lead bromide (MAPbBr3, without intentional doping) as the basis for the formation of a p–n junction. MAPbBr3 films deposited on TiO2 are slightly n-type, whereas in a full device they are strongly p-type. The charge transfer between the metal electrode and the halide perovskite (HaP) film is shown to determine the dominant charge carrier type of the HaP and, thus, also of the final cells. Usage of Pt, Au and Pb as metal electrodes shows the effects of metal work function on minority carrier diffusion length and majority carrier concentration in the HaP, as well as on built-in voltage, band bending, and open circuit voltage (VOC) within a solar cell. VOC > 1.5 V is demonstrated. The higher the metal WF, the higher the carrier concentration induced in the HaP, as indicated by a narrower space charge region and a smaller minority carrier diffusion length. From the analysis of bias-dependent electron beam-induced currents, the HaP carrier concentrations are estimated to be ∼ 1 × 1017 cm−3 with Au and 2–3 × 1018 cm−3 with Pt. A model in which type-inversion stretches across the entire film width implies formation of the p–n junction away from the interface, near the back-contact metal electrode. This work highlights the importance of the contact metal on device performance in that contact engineering can also serve to control the carrier concentration in HaP.

Graphical abstract: Type-inversion as a working mechanism of high voltage MAPbBr3(Cl)-based halide perovskite solar cells

Supplementary files

Article information

Article type
Paper
Submitted
08 Dec 2016
Accepted
23 Jan 2017
First published
26 Jan 2017

Phys. Chem. Chem. Phys., 2017,19, 5753-5762

Type-inversion as a working mechanism of high voltage MAPbBr3(Cl)-based halide perovskite solar cells

N. Kedem, M. Kulbak, T. M. Brenner, G. Hodes and D. Cahen, Phys. Chem. Chem. Phys., 2017, 19, 5753 DOI: 10.1039/C6CP08392G

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