Issue 81, 2016
From the journal:

Chemical Communications

When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK)†

Yaguang Zhao,‡a   Xu Liu,‡a   Yuchu Liu,‡a   Zhenqiang Wu,a   Xianyuan Zhaoa  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare EarthMaterials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn

Abstract

Photo responsive polyethyl vinyl ketone (PEVK) and various block copolymers were prepared through the visible light induced cobalt mediated radical polymerization (CMRP) process. The first order kinetics and linear increase in molecular weight with conversion demonstrated a well-behaved system. Chain extension experiments showed the retention of the living end of PEVK.

Graphical abstract: When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK)

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Article information

DOI
https://doi.org/10.1039/C6CC06254G
Article type
Communication
Submitted
28 Jul 2016
Accepted
07 Sep 2016
First published
12 Sep 2016

Chem. Commun., 2016,52, 12092-12095

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When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK)

Y. Zhao, X. Liu, Y. Liu, Z. Wu, X. Zhao and X. Fu, Chem. Commun., 2016, 52, 12092 DOI: 10.1039/C6CC06254G

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