Issue 62, 2016
From the journal:

Chemical Communications

Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme†

Mingpan Cheng,ab   Yinghao Li,ab   Jun Zhou,a   Guoqing Jia,a   Sheng-Mei Lu,a   Yan Yanga  and  Can Li*a  

* Corresponding authors

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: canli@dicp.ac.cn

b University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing, China

Abstract

Enantioselective sulfoxidation reaction is achieved for the first time by a DNA metalloenzyme assembled with the human telomeric G-quadruplex DNA and Cu(II)–4,4′-bimethyl-2,2′-bipyridine complex, and the mixed G-quadruplex architectures are responsible for the catalytic enantioselectivity and activity.

Graphical abstract: Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme

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Article information

DOI
https://doi.org/10.1039/C6CC03016E
Article type
Communication
Submitted
11 Apr 2016
Accepted
23 Jun 2016
First published
23 Jun 2016

Chem. Commun., 2016,52, 9644-9647

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Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme

M. Cheng, Y. Li, J. Zhou, G. Jia, S. Lu, Y. Yang and C. Li, Chem. Commun., 2016, 52, 9644 DOI: 10.1039/C6CC03016E

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