Issue 5, 2016

Novel visible-light-driven Fe2O3/Ag3VO4 composite with enhanced photocatalytic activity toward organic pollutants degradation

Abstract

In this study, a new type of high-performance visible light photocatalyst Fe2O3/Ag3VO4 was prepared by a two-step method. Fe2O3 was prepared by a solvothermal method first and then the Fe2O3/Ag3VO4 photocatalyst was synthesized with different mass ratios by a simple chemical precipitation method. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), UV-vis absorption spectroscopy (in DRS mode), and electrochemical impedance spectroscopy (EIS) were applied to characterize the as-prepared samples. The results showed that the as-prepared photocatalyst was uniform in the shape of particles. Photocatalytic properties of the as-prepared samples were evaluated by degrading RhB under visible light. The results showed that 1% Fe2O3/Ag3VO4 composite presented the highest photocatalytic activity. After 60 min, 96.1% of RhB was degraded by 1% Fe2O3/Ag3VO4 composite. Finally, trapping experiments confirmed that the hole (h+) and superoxide free radical (˙O2) were the main active species in degrading RhB.

Graphical abstract: Novel visible-light-driven Fe2O3/Ag3VO4 composite with enhanced photocatalytic activity toward organic pollutants degradation

Article information

Article type
Paper
Submitted
01 Nov 2015
Accepted
14 Dec 2015
First published
17 Dec 2015

RSC Adv., 2016,6, 3600-3607

Novel visible-light-driven Fe2O3/Ag3VO4 composite with enhanced photocatalytic activity toward organic pollutants degradation

Y. Xu, L. Jing, X. Chen, H. Ji, H. Xu, H. Li, H. Li and Q. Zhang, RSC Adv., 2016, 6, 3600 DOI: 10.1039/C5RA22912J

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