Issue 93, 2015

Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions. A catalytic and atom economic route for carbocycles and heterocycles

Abstract

Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions are important tools which have constantly grown over several years. This review summarizes and highlights their various aspects such as development of activated alkenes, electrophiles and catalysts both in achiral and chiral fashion, use of non conventional electrophiles, applications in total synthesis. Selected miscellaneous reports of internal promoters, cycloadditions, and non conventional routes for IMBH adduct have also been presented, along with future projections.

Graphical abstract: Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions. A catalytic and atom economic route for carbocycles and heterocycles

Article information

Article type
Review Article
Submitted
11 Jul 2015
Accepted
28 Aug 2015
First published
08 Sep 2015

RSC Adv., 2015,5, 75923-75946

Author version available

Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions. A catalytic and atom economic route for carbocycles and heterocycles

K. Chandra Bharadwaj, RSC Adv., 2015, 5, 75923 DOI: 10.1039/C5RA13611C

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