Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages

Yu-Teng Zhang; Xin-Long Wang; En-Long Zhou; Xue-Song Wu; Bai-Qiao Song; Kui-Zhan Shao; Zhong-Min Su

doi:10.1039/C5DT04764A

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Polyoxovanadate-based organic–inorganic hybrids: from {V₅O₉Cl} clusters to nanosized octahedral cages†

Yu-Teng Zhang,^a Xin-Long Wang,*^a En-Long Zhou,^a Xue-Song Wu,^a Bai-Qiao Song,^a Kui-Zhan Shao^a and Zhong-Min Su*^a

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* Corresponding authors

^a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, People's Republic of China
E-mail: wangxl824@nenu.edu.cn, zmsu@nenu.edu.cn

Abstract

Three polyoxovanadate-based metal–organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V₅O₉Cl} cluster connected by linear bidentate ligands (H₂L1 = H₂BDC, H₂L2 = H₂BDC-NH₂, H₂L3 = H₂BDC-Br), respectively.

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Article information

DOI: https://doi.org/10.1039/C5DT04764A
Article type: Communication
Submitted: 07 Dec 2015
Accepted: 25 Jan 2016
First published: 27 Jan 2016

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Dalton Trans., 2016,45, 3698-3701

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Polyoxovanadate-based organic–inorganic hybrids: from {V₅O₉Cl} clusters to nanosized octahedral cages

Y. Zhang, X. Wang, E. Zhou, X. Wu, B. Song, K. Shao and Z. Su, Dalton Trans., 2016, 45, 3698 DOI: 10.1039/C5DT04764A

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Dalton Transactions