Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur

W. Delaunay; R. Szűcs; S. Pascal; A. Mocanu; P.-A. Bouit; L. Nyulászi; M. Hissler

doi:10.1039/C5DT04154F

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Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur†

W. Delaunay,^a R. Szűcs,^ab S. Pascal,^a A. Mocanu,^a P.-A. Bouit,^a L. Nyulászi*^b and M. Hissler*^a

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* Corresponding authors

^a Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: muriel.hissler@univ-rennes1.fr

^b Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, H-1111 Budapest, Hungary

Abstract

In this work, we report on the synthesis of polyaromatic hydrocarbons containing phosphole and thiophene rings at the edge. The ring-closure reactions have been investigated by theoretical calculations. The optical and electrochemical properties and density functional theory calculations showed that the properties depend on the relative position of these five membered rings in the PAH structure.

This article is part of the themed collection: Phosphorus Chemistry: Discoveries and Advances

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DOI: https://doi.org/10.1039/C5DT04154F
Article type: Paper
Submitted: 22 Oct 2015
Accepted: 18 Nov 2015
First published: 20 Nov 2015
This article is Open Access

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Dalton Trans., 2016,45, 1896-1903

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Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur

W. Delaunay, R. Szűcs, S. Pascal, A. Mocanu, P.-A. Bouit, L. Nyulászi and M. Hissler, Dalton Trans., 2016, 45, 1896 DOI: 10.1039/C5DT04154F

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Dalton Transactions

Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur†

Abstract

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Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur

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