Issue 59, 2015
From the journal:

Chemical Communications

Iridium-catalyzed allyl–allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes†

Qianjia Yuan,a   Kun Yao,b   Delong Liub  and  Wanbin Zhang*ab  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China
E-mail: wanbin@sjtu.edu.cn
Fax: +21 5474 3265
Tel: +21 5474 3265

b School of Pharmacy, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China

Abstract

An efficient Ir-catalyzed allyl–allyl cross-coupling reaction of allylic carbonates with (E)-1,3-diarylpropenes was developed to form linear allylated products, 1,5-dienes, regioselectively in excellent yields and with high turnover numbers (up to 2000 S/Ir).

Graphical abstract: Iridium-catalyzed allyl–allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes

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Article information

DOI
https://doi.org/10.1039/C5CC04085J
Article type
Communication
Submitted
19 May 2015
Accepted
12 Jun 2015
First published
12 Jun 2015

Chem. Commun., 2015,51, 11834-11836

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Iridium-catalyzed allyl–allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes

Q. Yuan, K. Yao, D. Liu and W. Zhang, Chem. Commun., 2015, 51, 11834 DOI: 10.1039/C5CC04085J

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