Issue 44, 2015
From the journal:

Chemical Communications

A donor–acceptor conjugated block copolymer of poly(arylenevinylene)s by ring-opening metathesis polymerization†

Shu-Wei Changa  and  Masaki Horie*a  

* Corresponding authors

a Department of Chemical Engineering, National Tsing-Hua University, 101, Section 2, Kuang-Fu Road, Hsinchu, 30013 Taiwan
E-mail: mhorie@mx.nthu.edu.tw

Abstract

Novel conjugated cyclophanes comprising electron donating cyclopentadithiophene-vinylene and accepting dithienobenzothiadiazole-vinylene have been synthesized by McMurry coupling. Ring-opening metathesis polymerization (ROMP) of the acceptor monomer and the subsequent addition of the donor monomer allows the preparation of a fully conjugated diblock copolymer. The diblock copolymer exhibits multiple optical and electrochemical functions.

Graphical abstract: A donor–acceptor conjugated block copolymer of poly(arylenevinylene)s by ring-opening metathesis polymerization

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Article information

DOI
https://doi.org/10.1039/C5CC00498E
Article type
Communication
Submitted
18 Jan 2015
Accepted
15 Apr 2015
First published
27 Apr 2015

Chem. Commun., 2015,51, 9113-9116

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A donor–acceptor conjugated block copolymer of poly(arylenevinylene)s by ring-opening metathesis polymerization

S. Chang and M. Horie, Chem. Commun., 2015, 51, 9113 DOI: 10.1039/C5CC00498E

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