Issue 30, 2015
From the journal:

Chemical Communications

The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(i) complexes of a bis(aldimino)pyridine ligand†

Blake R. Reed,a   Sebastian A. Stoian,c   Richard L. Lord*b  and  Stanislav Groysman*a  

* Corresponding authors

a Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA
E-mail: groysman@chem.wayne.edu

b National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida, USA
E-mail: lordri@gvsu.edu

c Department of Chemistry, Grand Valley State University, Allendale, Michigan 49401, USA

Abstract

Reduction of bis(aldimino)pyridine nickel(II) dihalide forms a non-planar bis(aldimino)pyridine nickel(I) halide. Unlike the previously reported square-planar bis(ketimino)pyridine nickel chloride, for which the spin density was localized on the ligand, the present species demonstrate Npy–Ni–X angles of 156°–162° and significant spin density at the metal inferred from EPR measurements and DFT calculations.

Graphical abstract: The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(i) complexes of a bis(aldimino)pyridine ligand

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Article information

DOI
https://doi.org/10.1039/C5CC00203F
Article type
Communication
Submitted
09 Jan 2015
Accepted
27 Jan 2015
First published
27 Jan 2015

Chem. Commun., 2015,51, 6496-6499

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The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(I) complexes of a bis(aldimino)pyridine ligand

B. R. Reed, S. A. Stoian, R. L. Lord and S. Groysman, Chem. Commun., 2015, 51, 6496 DOI: 10.1039/C5CC00203F

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