Issue 24, 2015
From the journal:

RSC Advances

Spontaneous resolution of P and M helical copper(ii) MOFs built from achiral precursors†

Anik Bhattacharyyaa  and  Shouvik Chattopadhyay*a  

* Corresponding authors

a Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata-700032, India
E-mail: shouvik.chem@gmail.com
Tel: +913324572147

Abstract

Two enantiomorphic (P and M) helical coordination polymers of [Cu(μ1,3-N3)(L)]n {HL = 2-(dimethylamino)ethyliminomethylnaphthalen-2-ol} have been synthesized by the self-assembly of the achiral precursors via spontaneous resolution. The structures have been confirmed by single crystal X-ray crystallography. Solid-state circular dichroism spectra have confirmed the chirality of both P and M helical chains.

Graphical abstract: Spontaneous resolution of P and M helical copper(ii) MOFs built from achiral precursors

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Article information

DOI
https://doi.org/10.1039/C4RA17334A
Article type
Paper
Submitted
31 Dec 2014
Accepted
21 Jan 2015
First published
21 Jan 2015

RSC Adv., 2015,5, 18252-18257

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Spontaneous resolution of P and M helical copper(II) MOFs built from achiral precursors

A. Bhattacharyya and S. Chattopadhyay, RSC Adv., 2015, 5, 18252 DOI: 10.1039/C4RA17334A

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